Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others. IARC Monogr Eval Carcinog Risks Hum, 97: 1–510. 1993. MATERIAL SAFETY DATA SHEET – MSDS Product: VINYL CHLORIDE MONOMER Page 1 of 8 SDS No. Public Health Service, U.S. Department of Health and Human Services, Atlanta, GA. 1990. Environmental Criteria and Assessment Office, Office of Health and Environmental Assessment, Office of Research and Development, Cincinnati, OH. If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped.

P202 Do not handle until all safety precautions have been read and understood. Epidemiological studies have suggested an association between men occupationally exposed to vinyl chloride and miscarriages in their wives' pregnancies although other studies have not supported these findings. Aerobic biodegradation of vinyl chloride was measured in sediment at two sites in Denmark; >99% was removed in 204 and 274 days(4). <> This produces toxic and corrosive fumes of hydrogen chloride and phosgene. number 09019TO without the first two letters. The biodegradation half-life of vinyl chloride in aerobic waters was reported as 28 days(5). you enter 062K1064. 75-01-4 RTECS No. From our library of Related Content, Sigma-Aldrich presents Carcinogen Selector - Digestive System - LiverKeywords: Cancer, Carcinogens, Respiratory, The Carcinogen Selector gives researchers the ability to select carcinogens by the mouse organs that they promote cancer in. Questions? May cause respiratory tract irritation. Service Tel: +86-571-87759741, Marketing Tel: +86-571-89739798 skype, Copyright©2010-2020 Guidechem 浙B2-20090288-37, Recommended use of the chemical and restrictions on use, Classification of the substance or mixture, GHS label elements, including precautionary statements, Other hazards which do not result in classification, Description of necessary first-aid measures, Most important symptoms/effects, acute and delayed, Indication of immediate medical attention and special treatment needed, if necessary, Specific hazards arising from the chemical, Special protective actions for fire-fighters, Personal precautions, protective equipment and emergency procedures, Methods and materials for containment and cleaning up, Conditions for safe storage, including any incompatibilities, Individual protection measures, such as personal protective equipment (PPE), Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code, Safety, health and environmental regulations specific for the product in question, 3H-Indolium, 1,3,3-trimethyl-2-[2-(1-methyl-2-phenyl-1H-indol-3-yl)ethenyl]-, chloride (1:1), Ethane,1,2-dibromo-1-chloro- (6CI,7CI,8CI,9CI), VINYL CHLORIDE/VINYL ACETATE/MALEIC ACID TERPOLYMER, 1H-Indolium,1-[2-(1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)ethylidene]-2-methyl-,chloride (1:1), 1H-Indole,2,3-dihydro-1,3,3-trimethyl-2-[2-(2-methyl-3H-indol-3-ylidene)ethylidene]-,hydrochloride (1:1), 1H-Indolium,1-[2-(1,3-dihydro-1,3,3-trimethyl-2H-indol-2-ylidene)ethylidene]-2,3-dihydro-2-methyl-,chloride (1:1), Vinyl chloride pressure tin with 250 ml ~225 G net, For industry use only. STBB0728K9 - enter the lot number STBB0728 without the filling-code 62K1064 – you will only find the COO if ��(�� (�� (�� ���������������A���_�>��ҧ��_k���Οm On treatment with strong alkalis at high temperatures it loses hydrogen chloride. Vinyl chloride forms explosive mixtures with air in a wide range; the LEL and UEL values are 3.6% and 33.0% by volume in air, respectively. Inhalation: Show this safety data sheet to the doctor in attendance. In many cases a COA can be faxed Exposure to vinyl chloride occurs mainly in the workplace. Environmental dust in a plant for the production of polyvinyl chloride Ann Ist Super Sanita, 13: 189–198. P381 In case of leakage, eliminate all ignition sources. 12.3 Bioaccumulative potential. National Toxicology Information Program, National Library of Medicine, Bethesda, MD. Refer for medical attention. NIOSH usually recommends that occupational exposures to carcinogens be limited to the lowest feasible concentration. Need larger quantities for your development, manufacturing or research applications? Arbeitsmedizin, Sozialmedizin, Praventivmedizin, 12: 280–283, Casula D, Cherchi P, Spiga G, Spinazzola A (1977). More important for COO: enter a "0" if only two numbers are (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), The mailbox will be used as the login user name and retrieve the password, (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), Other AdditivesVolatiles/ Semivolatiles, 2,3-Dichloro-5,6-dicyano-1,4-benzoquinone, jkinfo@jkchemical.com;market6@jkchemical.com, VINYL CHLORIDE Preparation Products And Raw materials. “Vinyl Chloride Polymers” Encyclopedia of Polymer Science and Engineering. cause respiratory and digestive tract irritation. search was unable to find the COA you are looking for, you will be Eye: Chromosome tests in vinyl chloride exposed workers] (Ger.). Lot and Batch Numbers can be found on a product's label Handle with gloves. NIOSH considers vinyl chloride to be a potential occupational carcinogen. © 2020  Merck KGaA, Darmstadt, Germany and/or its affiliates. 1 0 obj <>/XObject<>>>>> endobj 2 0 obj <> endobj 3 0 obj <> endobj 4 0 obj <>/FontDescriptor 3 0 R/CIDToGIDMap/Identity/W[0[750 277 666 222 556 500 222 722]8 9 556 10[333]11 12 556 13[500]14 15 277 16[666 277 333 833 333 500 333 833 777 556 500 277 666 277 666]31 35 556 36[722 556 277]39 41 556 42 43 722 44[556 666]46 48 556 49[610 666 722 556 277 777 610]56 57 666 58[500]59 60 556 61[722 943 666 500 222 500 722 277 354 399 277 777 277 889 500]76 77 583 78[222 610 389]]>> endobj 5 0 obj <>stream Several case reports suggest that male sexual performance may be affected by vinyl chloride. �җq�?��|9� Dn� ����F�?��_�� ���� ���/��yZ[���j|F'���@�>�?O�w�6��o�0��� ��q_z�>��q�?��|6���#� ��}�� Q�O������|V���-�� �� ���>_�i|F� � P280 Wear protective gloves/protective clothing/eye protection/face protection. Material:Vinyl resin VAMA - 6 - SARA 311/312 Hazard Class: This product does not present any SARA 311/312 hazards. IARC (1974). Vinyl chloride had a biodegradation rate of 1.456 ug/g soil/hr in soil from Skellingsted landfill in Holback, Denmark, incubated with methane(6). Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. Vinyl chloride ≥99.5%; CAS Number: 75-01-4; EC Number: 200-831-0; Synonym: Chloroethylene; Linear Formula: C2H3Cl; find Sigma-Aldrich-387622 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. xڤ� |TE�ZUw�v���t��Ig�@��%�U�U���AdAA������:.��� @@3�����ۨ�0*:F��q�t�Su�C��{���^:�޺u��:����S� t��R�q��r�$�����0G�}�������S�7�G�� ���������}M%q� m��ۃ0��|ϼ��7�������?�u����KpG��H� ����#��� �c�#��� �� � w !1AQaq"2�B���� #3R�br� Experimental carcinogen. Hazardous Substances Data Bank (HSDB, online database). 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Perform CPR as necessary. 003 MANUFACTURER EMERGENCY TELEPHONE No. KU9625000. : SDS-125-CLP 1/11 Danger SECTION 1: Identification of the substance/mixture and of the company/undertaking Trade name : Vinyl chloride Large fires of this material are practically inextinguishable.The gas is heavier than air and may travel along the ground; distant ignition possible. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Personal protection: complete protective clothing including self-contained breathing apparatus. Geneva: World Health Organization. Caution! Avoid formation of dust and aerosols. Safety glasses with side-shields conforming to EN166. | Privacy. /Carbon tetrachloride and related compounds/. Appearance: Off - White Powder. Immediately flush contaminated eyes with gently flowing water. Store in a well-ventilated place. The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Breathing high levels of vinyl chloride for short periods of time can cause dizziness, sleepiness, unconsciousness, and at extremely high levels can cause death. Remove all ignition sources.

a��#� ��h�7���v0�q�1�a;>�'�G>��}�m�#�3�����@C�5�����k>��8-@ނ��2"��M�cف�G>�3�8�@x?Z >���X́�����QA��5>���?��SNT�CmKޜ��c;>��-|��O�X��7�!Z�x́��c��l��~���G�C����� Wash hands before breaks and at the end of workday. INHALATION: high concentrations cause dizziness, anesthesia, lung irritation. Health Effects Assessment Summary Tables. Gas is heavier than air and may travel considerable distance to a source of ignition and flash back. Absorb small amounts of spill with natural or synthetic sorbents, shovel into containers with covers. 1 ppm = 2.56 mg/m 3. Evacuate personnel to safe areas. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. �Jn ��ls� �Ai4=�����&g�g!|c9��!��_+z}�5�d���ID��2�O�n�2�3��b�R9��+Я��N�ߐ�&�L��{ȃz��P����/��M�{���١]�~���C� Land Spill: Construct barriers to contain spill. If patient is not breathing, start artificial respiration, preferably with a demand-valve resuscitator, bag-valve-mask device, or pocket mask, as trained. Site Use Terms

Max: 1: Purity, as VCM % wt: 99,9-2: Moisture Cont. IDLH. Cool all affected containers with flooding quantities of water. The BCF value of vinyl chloride in green algae was reported as 40(2). 1997. Agency for Toxic Substances and Disease Registry (ATSDR). ������ 7�K�0� � ���^��a���#�J��q�?��������Μ�_�\ϼ��3�����K���g��pG��H. {���93��?�����|� �~$����X��� ��b ���Ҿ�+!ʸ!�b�

No smoking. Vinyl chloride Date of issue: 10/11/2010 Revision date: 24/12/2015 : Version: 1.0 SDS-125-CLP Air Liquide UK Ltd. Station Road, Coleshill B46 1JY Birmingham United Kingdom 01675462424 EN (English) SDS Ref. Many oxidizing agents apparently initiate polymerization (oxides of nitrogen, O2, etc.). Cancer suspect K9. Qatar Vinyl Company Ltd. P. O. Avoid breathing dust. Sigma-Aldrich Products are sold exclusively through Sigma-Aldrich, Inc. REGULATORY INFORMATION-----Up to Table of Contents U.S.
P308+P313 IF exposed or concerned: Get medical advice/ attention. Ventilation. �� Do not induce vomiting.

Animal studies have reported decreased fetal weight and birth defects at levels that are also toxic to maternal animals in the offspring of rats exposed to vinyl chloride through inhalation. In some cases, a COA may not be available on-line. Rep Carcinog, 11: 1–A32. According to a classification scheme(3), these BCFs suggest that bioconcentration in aquatic organisms is low(SRC). This colorless compound is an important industrial chemical chiefly used to produce PVC. 05427ES–021 - enter the lot number 05427ES without the filling-code See Chemical Dangers. NIOSH REL Ca See Appendix A OSHA PEL [1910.1017] TWA 1 ppm C 5 ppm [15 … Ca [N.D.] See: IDLH INDEX . Luxembourg. Several epidemiological studies have reported an association between vinyl chloride exposure in pregnant women and an increased incidence of birth defects, while other studies have not reported similar findings. 1/4  in., stainless steel.

Avoid contact with skin and eyes. IARC (1987). Special Hazards of Combustion Products: Forms highly toxic combustion products such as hydrogen chloride, phosgenic, and carbon monoxide. REGULATIONS: TSCA INVENTORY STATUS: Y TSCA 12(b) EXPORT NOTIFICATION: Not listed. AEROBIC: Limited existing data indicate that vinyl chloride is resistant to biodegradation in aerobic systems(1,2). Vinyl chloride may decom pose under fire conditions, producing the toxic gases carbon monoxide and hydrogen chloride. FY1997 Update. Behavior in Fire: Container may explode in fire. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Stainless steel control valves Z146951, Z187224 or either of stainless steel regulators Z148504 and Z148512 and a "T"-purge valve Z151661 is recommended. 71 0 obj